Capping Principle||Organometallic Chemistry CSIR NET/GATE Inorganic Chemistry

In organometallic chemistry cluster geometry is most important part also lots of people are confuse about capping principle. Here i will clear all the doubt.

Capping Principle Organometallic Chemistry PDF

Video lecture-

Peroxide||Organic Reagent Series||CSIR NET/GATE/IIT JAM/M.SC CHEMISTRY

Peroxides are a group of compounds with the structure 

R−O−O−R, where R = any element.

The O−O group in a peroxide is called the peroxide group or peroxo group. 

The nomenclature is somewhat variable.

PDF-PEROXIDE REAGENT PDF

Diastereoselctivity In Acyclic Alkene||Organic Chemistry From Clayden

In organic chemistry tge stereoselectivity is rhe most confusing topic.here is tge odf of diastereoselectivity from clayden book which will clear all your doubts related to the stereoselectivity.

PDF-Diastereoselectivity In Acyclic Alkene pdf

Bayer Villiger Oxidation||Reagent Chemistry

Baeyer-Villiger Oxidation

In Baeyer Villiger oxidation a carbonyl

Compound and an aromatic peracid react via insertion of the peroxo-O atom next to the C=O bond of the carbonyl compound.

The Baeyer–Villiger Reaction is a commonly used oxidation reaction in organic synthesis is the conversion of carbonyl compounds into the corresponding esters or lactones

PDF-Baeyer Oxidation pdf

m-CPBA REAGENT||oxidizing Reagent||CSIR NET CHEMISTRY

 meta-Chloroperoxybenzoic acid (mCPBA or mCPBA) is a peroxycarboxylic acid. A white solid, it is used widely as an oxidant in organic synthesis. 

mCPBA is often preferred to other peroxy acids because of its relative ease of handling.

mCPBA is a strong oxidizing agent that may cause fire upon contact with flammable material.

PdF-m-CPBA REAGENT PDF

OPPENAUER OXIDATION|CSIR NET REAGENT CHEMISRTY

Oppenauer Oxidation is the process of conversion of secondary alcohols to ketones by selective oxidation. This reaction is named after Rupert Viktor Oppenauer. Oxidation reaction takes place in the presence of [Al(i-Pro)3] in excess of acetone.

It is an aluminium alkoxide catalysed the oxidation of a secondary alcohol to the corresponding ketone. This is reverse of the Meerwein Ponndorf Verley reduction. It is a very good method to oxidize allylic alcohols to α, β- unsaturated ketones.

PdF-OPPENAUER OXIDATION PDF

Isolobal Analogy||Organometallic Chèmistry

 

In previous post we learn about Metal metal bondong in low nuclear carbonyl clusters.

Now before moving on high nuclear carbonyl cluster we should talk about isolobal analogy.

PdF-Isolobal analogy|Organometallic chemistry